Methoxydiethylborane

Base Information

  • PRODUCT:Methoxydiethylborane
  • CAS.:7397-46-8
  • MF:C5H13BO
  • Molecular Weight:99.9686
  • Purity:99%

Product Details

CAS: 7397-46-8

MF: C5H13BO

Cost-effective and customizable Methoxydiethylborane 7397-46-8 in stock

  • Molecular Formula:C5H13BO
  • Molecular Weight:99.9686
  • Vapor Pressure:84.8mmHg at 25°C 
  • Refractive Index:n20/D 1.387(lit.)  
  • Boiling Point:83.2 °C at 760 mmHg 
  • Flash Point:20°F 
  • PSA:9.23000 
  • Density:0.717 g/cm3 
  • LogP:1.66410 

Methoxydiethylborane(Cas 7397-46-8) Usage

InChI:InChI=1/C5H13BO/c1-4-6(5-2)7-3/h4-5H2,1-3H3

7397-46-8 Relevant articles

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Mikhailov,B.M. et al.

, (1975)

-

-

Noeth,H.,Vahrenkamp,H.

, p. 23 - 36 (1968)

-

Process for synthesizing diethyl alkoxy borane

-

Paragraph 0012, (2017/02/17)

The invention discloses a process for sy...

Syntheses, structures, and coordination of diborylbipyridines and bipyridinediborates

Weis, Norbert,Pritzkow, Hans,Siebert, Walter

, p. 393 - 398 (2007/10/03)

6,6'-Bis(diethylboryl)-2,2'-bipyridine (...

Hydroboration with haloborane/trialkylsilane mixtures

Soundararajan, Raman,Matteson, Donald S.

, p. 4157 - 4166 (2008/10/09)

Trialkylsilanes or dialkylsilanes react ...

A Novel Method for the In Situ Generation of Alkoxydialkylboranes and Their Use in the Selective Preparation of 1,3-Syn Diols

Chen, Kau-Ming,Gunderson, Karl G.,Hardtmann, Goetz E.,Prasad, Kapa,Repic, Oljan,Shapiro, Michael J.

, p. 1923 - 1926 (2007/10/02)

An in situ method for generating Et2BOCH...

7397-46-8 Process route

methanol
67-56-1

methanol

diethylboric acid
4426-31-7

diethylboric acid

diethyl methoxy borane
7397-46-8

diethyl methoxy borane

Conditions
Conditions Yield
In n-heptane; Reflux;
methanol
67-56-1

methanol

triethylsilane
617-86-7

triethylsilane

ethene
74-85-1

ethene

boron trichloride
10294-34-5

boron trichloride

Trimethyl borate
121-43-7,63156-11-6

Trimethyl borate

ethylboronic acid dimethyl ester
7318-82-3

ethylboronic acid dimethyl ester

diethyl methoxy borane
7397-46-8

diethyl methoxy borane

Conditions
Conditions Yield
In methanol; xylene; byproducts: Et3SiCl; Ar-atmosphere; mixing BCl3, Et3SiH and C2H4, distillation of EtBCl2, addn. of MeOH; collection (distillation); NMR spectroscopy;
72%
In methanol; dichloromethane; byproducts: Et3SiCl, HCl; Ar-atmosphere; mixing BCl3 and Et3SiH at -78°C, bubling of C2H4, distillation of EtBCl2 and Et2BCl, addn. of MeOH at -78°C, warming to 0°C; collection (distillation); NMR spectroscopy;
In neat (no solvent); byproducts: Et3SiCl; Ar-atmosphere; mixing BCl3, Et3SiH and C2H4, addn. of MeOH; collection (distillation); NMR spectroscopy;

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7397-46-8 Downstream products

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    diethyl (pyridin-4-yl)borane

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