CAS: 461-58-5
MF: C2H4N4
Appearance: white powder
Chemical Composition and Structure |
Cyanoguanidine is a guanidine derivative in which one of the amino hydrogens of guanidine is substituted by a cyano group (-CN). It is composed of carbon, nitrogen, and hydrogen atoms. |
Production Methods |
Cyanoguanidine can be produced synthetically by treating cyanamide with a base. |
Application |
Dicyanodiammonia, abbreviated as dicy or DCD. It is an organic substance with the chemical formula of c2h4n4. It is a dimer of cyanamide and a cyano derivative of guanidine. Chemical formula c2h4n4. White crystalline powder. Soluble in water, alcohol, ethylene glycol and dimethylformamide, almost insoluble in ether and benzene. Stable when dry. It is a guanidine in which one of the amino hydrogens of guanidine itself is substituted by a cyano group. It is used in the manufacture of fertilizers, pharmaceuticals, explosives, oil well drilling muds, and dyestuffs. It has a role as a curing agent, a flame retardant, a fertilizer, an explosive and a nitrification inhibitor. It is a member of guanidines and a nitrile. The application of nitrification inhibitors has been used as a strategy to promote N utilization efficacy and reduce N2O emissions in paddy Dicyandiamide (DCD) as a widely used nitrification inhibitor inhibits the activity of ammonium-oxidizing bacteria which results in longer ammonium retention and reduces the production of NO2?in soils. DCD efficacy was found to be related to DCD concentration, temperature, moisture, pH, and organic matter content. Studies have shown that leaching DCD from agricultural soils into aquatic ecosystems can strongly change the community composition of benthic stream bacteria and algae and influence stream nutrient cycling stoichiometry. Literature on the mechanisms and benefits of nitrification inhibitors is extensive but there are very few studies focused on the influence of DCD application on other microbes in paddy system. |
General Description |
Dicyandiamide is commonly used for the curing of epoxy resins. It is a nitrification inhibitor that is said to be capable of reducing nitrate (NO3-) leaching and nitrous oxide (N2O) emissions from grazed pasture soils. |
Flammability and Explosibility |
Nonflammable |
Synthesis |
The calcium hydrogen cyanide suspension obtained from the hydrolysis of calcium cyanamide is filtered under reduced pressure to remove the calcium hydroxide filter residue, and then carbon dioxide is introduced into the filtrate to precipitate the calcium in the form of calcium carbonate to obtain the cyanamide solution. It is polymerized under alkaline conditions, then filtered, cooled, crystallized, separated and dried to obtain dimer cyanamide. The temperature at the maximum rate of dicyandiamide formation is related to pH: pH is 9.7 at 50 ℃; PH 9.1 at 80 ℃; The pH is 8.8 at 100 ℃. After controlled polymerization under these conditions, the finished dicyandiamide is obtained by cooling, crystallization, separation and drying. The content of dicyandiamide in industrial products is 99%, and 4239kg of lime nitrogen (more than 21% nitrogen) is consumed per ton of products. |
Purification Methods |
Recrystallise cyanoguanidine from water or EtOH. [Beilstein 3 IV 160.] |
InChI:InChI=1/C2H4N4/c3-1-6-2(4)5/h(H4,4,5,6)/p+1
Nitrosation of cyanamide leads to unstab...
The microwave-enhanced synthesis of sulp...
Substituted o- and p-nitroanilines and m...
1-Benzoyl-2-phenylacetylene reacted with...
S-benzyl isothiocarbamide
N-Cyanoguanidine
phenylmethanethiol
Conditions | Yield |
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zerfaellt beim Schmelzpunkt;
|
S-benzylisothiourea hydrochloride
N-Cyanoguanidine
phenylmethanethiol
Conditions | Yield |
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|
azido-N-cyanoformamidinate
dicyandiazide
CYANAMID
nitrosoguanidine
6-piperidino-[1,3,5]-triazine-2,4-diamine
1-phenylbiguanide
2,4-diamino-6-(2-furyl)-1,3,5-triazine
2,4-diamino-6-(2′-pyridyl)-1,3,5-triazine